The PVD Wiki supports what are called structures, which is just a fancy term for associating wiki pages so that they can be read in a particular sequence (like a pamphlet or book). I've created a structure called 'PVD-Manual' which lays out wiki pages in a logical sequence that could be referenced like a manual. You can check the PVD-Manual out here --
http://www.nimidia.com/pvd_wiki/tiki-index.php?page=PVD-Manual. Navigation icons for moving through the pages are available at the top of the page.
As content is updated they are automatically reflected in the PVD-Manual. However, for new pages, these need to be added to the structure in order to be reflected in the manual. Anybody is welcome to do this (and I'll try to check for new pages that should be added to the manual as I can).
Additionally, I've enabled a feature called 'Multiple Print'. You can find this under the Wiki menu. This feature allows you to select pages and/or structures for printing. So, for example, if you want to print the PVD-Manual, you can select the PVD-Manual structure and print the entire manual. If you have a PDF Printer installed, you can print the manual to a PDF file for reference.
This feature is available for any page (or pages) you choose.
Wiki pages are already being updated to refect changes (and new features) that have been introduced with version 0.9.9.5 beta of PVD (such as support for remote database servers and permissions). These aren't in the PVD-Manual structure yet, but they will be soon.
Hope you enjoy.